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un:bose-einstein-statistics [2025/11/30 07:33] – [Bose–Einstein occupation curves] asadun:bose-einstein-statistics [2025/11/30 07:37] (current) asad
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 $$ $$
  
-Here the factor of 2 accounts for two photon polarization states. For massive bosonsthis factor is replaced by the appropriate spin degeneracy. This function expresses a key difference between classical and quantum statistics: the denominator can become small, allowing **large occupation of low-energy states**.+Here the factor of 2 accounts for two photon polarization states. For massive bosons this factor is replaced by the appropriate spin degeneracy \( g \). This function expresses a key difference between classical and quantum statistics: the denominator can become small, allowing large occupation of low-energy states.
  
-For photons, the variable \( \nu \) labels frequency, and this same distribution underlies the Planck spectrum of [[Blackbody radiation]]. For massive bosons, the energy is instead \( \epsilon = p^{2}/2m \), but the statistical form is identical:+For photons, the variable \( \nu \) labels frequency, and this same distribution underlies the Planck spectrum of [[Blackbody radiation]]. For massive bosons, the energy is instead \( \epsilon = p^{2}/(2m\), but the statistical form is identical:
  
 $$ $$
-f = \frac{g}{h^{3}} \frac{1}{e^{(\epsilon-\mu)/(kT)} - 1},+f = \frac{g}{h^{3}} \, \frac{1}{e^{(\epsilon-\mu)/(kT)} - 1}.
 $$ $$
  
-with \( g \) the spin degeneracy. The form of \( f \) therefore unifies the physics of blackbody photons and ideal Bose gases.+The form of \( f \) therefore unifies the physics of blackbody photons and ideal Bose gases.
  
 ===== Mean occupation of quantum states ===== ===== Mean occupation of quantum states =====
  
-The phase-space distribution function determines the **mean number of bosons occupying each single-particle quantum state**. Integrating \(f\) over a cell associated with the state \(i\) leads directly to the Bose–Einstein occupation number:+The phase-space distribution function determines the mean number of bosons occupying each single-particle quantum state. Integrating \( f \) over a phase-space cell associated with state \( i \) leads to the Bose–Einstein occupation number
  
 $$ $$
-\bar{n}_i = \frac{1}{\exp\!\left(\frac{\epsilon_i - \mu}{kT}\right) - 1}.+\bar{n}_i = \frac{1}{e^{(\epsilon_i - \mu)/(kT)} - 1}.
 $$ $$
  
-This quantity plays the same role for massive bosons that the photon distribution function plays for radiation. Summing over all states,+This quantity plays the same role for massive bosons that the photon distribution function plays for radiation. Summing over all states gives
  
 $$ $$
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 $$ $$
  
-In the continuum limit with density of states \(g(\epsilon)\),+In the continuum limit with density of states \( g(\epsilon) \),
  
 $$ $$
 n = \frac{N}{V} n = \frac{N}{V}
-  = \int_0^\infty \frac{g(\epsilon)}{\exp[(\epsilon-\mu)/(kT)- 1} \, d\epsilon.+  = \int_0^\infty \frac{g(\epsilon)}{e^{(\epsilon-\mu)/(kT)- 1} \, d\epsilon.
 $$ $$
  
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 $$ $$
  
-the Bose–Einstein distribution reduces to the Maxwell–Boltzmann form,+the Bose–Einstein distribution reduces to the Maxwell–Boltzmann form
  
 $$ $$
-\bar{n}_i \approx \exp\!\left(-\frac{\epsilon_i-\mu}{kT}\right),+\bar{n}_i \approx e^{-(\epsilon_i-\mu)/(kT)},
 $$ $$
  
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 $$ $$
-f \approx \frac{g}{h^{3}} e^{-(\epsilon-\mu)/(kT)}.+f \approx \frac{g}{h^{3}} \, e^{-(\epsilon-\mu)/(kT)}.
 $$ $$
  
-Quantum statistical effects appear when the thermal de Broglie wavelength,+Quantum statistical effects appear when the thermal de Broglie wavelength
  
 $$ $$
 \lambda_{\mathrm{th}} \lambda_{\mathrm{th}}
-= \sqrt{\frac{2\pi\hbar^{2}}{m kT}},+= \sqrt{\frac{2\pi\hbar^{2}}{m kT}}
 $$ $$
  
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 $$ $$
-n\lambda_{\mathrm{th}}^{3} \gtrsim 1.+n \lambda_{\mathrm{th}}^{3} \gtrsim 1.
 $$ $$
  
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 ===== Bose–Einstein condensation ===== ===== Bose–Einstein condensation =====
  
-For a uniform ideal Bose gas, the chemical potential satisfies \( \mu \le \epsilon_{0} \). As the gas is cooled at fixed density, \( \mu \rightarrow \epsilon_{0} \), and the excited states are no longer capable of holding all particles. The excess particles accumulate in the ground state, producing macroscopic occupation:+For a uniform ideal Bose gas, the chemical potential satisfies \( \mu \le \epsilon_{0} \). As the gas is cooled at fixed density, \( \mu \to \epsilon_{0} \), and the excited states are no longer capable of holding all particles. The excess particles accumulate in the ground state, producing macroscopic occupation,
  
 $$ $$
-\bar{n}_{0} \rightarrow \text{large}.+\bar{n}_{0} \gg 1.
 $$ $$
  
-This is **Bose–Einstein condensation**, a striking manifestation of the Bose–Einstein distribution function. The condensation phenomenon is therefore the direct consequence of the form of \(f\) and the associated occupation numbers \(\bar{n}_i\): large phase-space density implies large ground-state occupation.+This is Bose–Einstein condensation, a striking manifestation of the Bose–Einstein distribution function. The condensation phenomenon is therefore the direct consequence of the form of \( f \) and the associated occupation numbers \( \bar{n}_i \): large phase-space density implies large ground-state occupation.
  
 In contrast, for photons the chemical potential is fixed to zero, and instead of condensing, photons redistribute themselves to form the blackbody spectrum. In contrast, for photons the chemical potential is fixed to zero, and instead of condensing, photons redistribute themselves to form the blackbody spectrum.
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 ===== Bose–Einstein occupation curves ===== ===== Bose–Einstein occupation curves =====
  
-To analyze how the Bose–Einstein distribution behaves, it is useful to define dimensionless variables,+To analyze how the Bose–Einstein distribution behaves, it is useful to define dimensionless variables
  
 $$ $$
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 $$ $$
  
-Small \(a\) (i.e., large \( \mu \)) enhances the low-energy peak of the distribution. The special case \(a=0\) corresponds exactly to the photon distribution function above.+Small \( a \) (that is, large \( \mu \)) enhances the low-energy peak of the distribution. The special case \( a = 0 \) corresponds exactly to the photon distribution function in blackbody radiation.
  
 <html> <html>
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 }; };
  
-// Axis labels with NO MathJax+// Axis labels with no MathJax
 const layout_be = { const layout_be = {
   margin: {l: 95, r: 20, t: 10, b: 60},   margin: {l: 95, r: 20, t: 10, b: 60},
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   * Large low-energy occupation arises because the denominator may become small as \( \mu \to \epsilon_{0} \).   * Large low-energy occupation arises because the denominator may become small as \( \mu \to \epsilon_{0} \).
   * Classical statistics emerges only when \( e^{(\epsilon-\mu)/(kT)} \gg 1 \), suppressing large occupation.   * Classical statistics emerges only when \( e^{(\epsilon-\mu)/(kT)} \gg 1 \), suppressing large occupation.
-  * Quantum degeneracy appears when \( n\lambda_{\mathrm{th}}^{3} \gtrsim 1 \), forcing the use of Bose–Einstein statistics.+  * Quantum degeneracy appears when \( n \lambda_{\mathrm{th}}^{3} \gtrsim 1 \), forcing the use of Bose–Einstein statistics.
   * Bose–Einstein condensation results directly from the inability of excited states to hold all particles as \( \mu \to \epsilon_0 \).   * Bose–Einstein condensation results directly from the inability of excited states to hold all particles as \( \mu \to \epsilon_0 \).
   * For photons, the condition \( \mu = 0 \) transforms the Bose–Einstein distribution into the Planck spectrum of blackbody radiation.   * For photons, the condition \( \mu = 0 \) transforms the Bose–Einstein distribution into the Planck spectrum of blackbody radiation.
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 ===== Inquiries ===== ===== Inquiries =====
   * Derive the phase-space distribution \( f = g h^{-3} [e^{(\epsilon-\mu)/(kT)} - 1]^{-1} \) from the grand canonical ensemble.   * Derive the phase-space distribution \( f = g h^{-3} [e^{(\epsilon-\mu)/(kT)} - 1]^{-1} \) from the grand canonical ensemble.
-  * Show how the occupation number \( \bar{n}_i \) emerges from integrating \(f\) over a state’s phase-space cell.+  * Show how the occupation number \( \bar{n}_i \) emerges from integrating \( f \) over a state’s phase-space cell.
   * Demonstrate explicitly how the Maxwell–Boltzmann limit arises from the Bose–Einstein distribution.   * Demonstrate explicitly how the Maxwell–Boltzmann limit arises from the Bose–Einstein distribution.
-  * Using \( n\lambda_{\mathrm{th}}^{3} \sim 1 \), estimate the temperature at which a dilute Bose gas becomes quantum degenerate. +  * Using \( n \lambda_{\mathrm{th}}^{3} \sim 1 \), estimate the temperature at which a dilute Bose gas becomes quantum degenerate. 
-  * Explain how varying \(a=-\mu/(kT)\) alters the shape of the occupation curves in the interactive figure.+  * Explain how varying \( a = -\mu/(kT) \) alters the shape of the occupation curves in the interactive figure.
  
un/bose-einstein-statistics.1764513225.txt.gz · Last modified: by asad

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